Usually polyphemus will stay copulated until the next day, after pairing in the evening. I am sure there
are exceptions.
The mass laying sounds abnormal.
My guess would be any ova are probably not fertilized, from either female.
I always keep ova for at least 14 days, sometimes longer, or unless the ova collapse and shrink,
then that is a clear sign of infertility. Most Saturniidae hatch in 10 days, give or take, others can take
much longer.
Use a small container, don't put any leaves in with ova, I use a petri dish for ova and mist the top of the dish
periodically.
Lastly, it's getting late for caterpillars, especially outdoors.